Precipitation titration

Titrations with precipitating providers are useful to get determining particular analytes e. g. Cl- can be determined when titrated with AgNO3.

Recognition of end point:


–Precipitation Type -- Mohr's technique

–Adsorption – Fajan's method

–For sterling silver analyses –Volhard method

•Sensors –Potentiometric or amperometric

The chemical types are also classified into:

1 ) Indicators responding with titrant forming particular color.

2 . Adsorption symptoms.

Indicators re-acting with the titrant:

Two methods will be discussed where this kind of indicators are applied; particularly: Mohr and Volhard.

I) Mohr way of determining chloride:

Chloride is usually titrated with AgNO3 remedy. A soluble chromate sodium is added as the indicator. This kind of produces a discolored color solution. When the anticipation of the chloride is total, the initially excess of Ag+ reacts with the indicator to precipitate reddish silver chromate: 2 Ag+(aq) + CrO42–(aq) → Ag2CrO4(s)

Yellowish red ppt The Mohr method must be performed for a pH about almost 8. This method is advantageous for deciding Cl- in neutral or unbuffered solutions such as moving water.

II) Volhard titration:

This really is an indirect titration process of the willpower of anions that medicine with silver precious metal like CL-, Br-, I-, SCN-, and it is preferred in acid (HNO3) solution. A measured more than AgNO3 can be added to ppt the neutron, and the more than Ag+ is determined by back titration with normal potassium thiocyanate solution: Ag+(aq) + Cl–(aq) → AgCl(s) + extra Ag+

excess Ag+(aq) + SCN–(aq) → AgSCN(s)

The end level is discovered by adding iron III (Fe3+) as ferric ammonium sulfate which forms a sencillo red complex with the 1st excess of titrant. Fe3+(aq) & SCN–(aq) → [FeSCN]2+(aq)

These kinds of indicators should never form a compound with the titrant that is more stable than the medicine or the color reaction will occur about addition of...